Prolonged contact with eyes or skin may cause irritation. The precautionary measures and guidance on safe use are as submitted to ECHA by registrants under the REACH Regulation. 2(b)(i) - Hazardous Agents, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, Workplace Signs - minimum requirements & signs on containers and pipes, Previous consultations on ECHA’s Executive Director Requests to the Committees, Applications for authorisation consultations, Harmonised classification and labelling consultations, ECHA Executive Director’s requests related to the CLH process, Consultation on potential candidates for substitution, Consultation on derogation to the exclusion criteria, ECHA's Executive Director Requests to the Committees, Consultation on a draft recommendation for amendment of Authorisation List entries, Consultations in the authorisation process, Occupational exposure limits - Call for comments and evidence, Occupational exposure limits - Previous calls for comments and evidence, Occupational exposure limits – Consultations on OEL recommendation, Derogations for the protection of cultural heritage, ECHA's current activities on restrictions, ECHA's completed activities on restriction, Information on Candidate List substances in articles table, Information from the Existing Substances Regulation (ESR), PBT/vPvB assessments under the previous EU chemicals legislation, Adopted opinions and previous consultations on applications for authorisation, Adopted opinions on restriction proposals, Mapping exercise – Plastic additives initiative, Occupational exposure limits substance evaluations, List of substances subject to POPs Regulation, Small and Medium-sized Enterprises (SMEs), Practical examples of chemical safety reports. 0000003770 00000 n The EU Ecolabel may not be awarded to substances or mixtures classified as such. Product Name: Fumaric acid Product Code: 106301 Chemical Name: Fumaric acid Index No: 607-146-00-X CAS No: 110-17-8 OTHER HAZARDS FIRE AND EXPLOSION HAZARD: May form combustible dust concentrations in air. FUMARIC ACID FOR SYNTHESIS is not on the REACH Candidate List FUMARIC ACID FOR SYNTHESIS is not on the REACH Annex XIV List 15.1.2. Fumaric acid. These notifications can be provided by manufacturers, importers and downstream users. : 682001: Relevant identified uses of the substance or mixture: Identified: Laboratory chemical uses: R&D: Uses advised against: HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. This substance has been found in the following regulatory activities (directly, or inheriting the regulatory context of a parent substance): This list represents a calculated inventory of substances based on the list of harmonized substances contained in Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). Its chemical formula is HO 2 CCH=CHCO 2 H. Maleic acid is the cis-isomer of butenedioic acid, whereas fumaric acid is the trans-isomer.It is mainly used as a precursor to fumaric acid, and relative to its parent maleic anhydride, maleic acid has few applications. Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements (EUH) or the. SAFETY DATA SHEET: FUMARIC ACID FUMARIC ACID F765.32 INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887) 1216 6th Ave N Kent WA 98032 Phone: 253-479-7000 HO2CCH:CHCO2H 116.07 Their reactions with bases, called "neutralizations", are accompanied by … 0000002725 00000 n This substance is used for the manufacture of: chemicals. Fumaric acid uses include paper sizing, food acidulant and UPR manufacture. The EC Inventory is a combination of three independent European lists of substances from the previous EU chemicals regulatory frameworks (EINECS, ELINCS and the NLP-list). SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. C&L Inventory . 0000001325 00000 n 8.5.1.1 Succinic, fumaric, and malic acid. The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. This section provides links to the list of precautions (precautionary statements) and to the guidance on safe use, if they have been provided in REACH registration dossiers. HAZARD SUMMARY * Fumaric Acid can affect you when breathed in. 0000005970 00000 n Special Hazards of Combustion Products: Irritating smoke containing maleic anhydride may form in fire. Gives off irritating or toxic fumes (or gases) in a fire. 0000003524 00000 n 0000032684 00000 n Substances listed in the EINECS, ELINCS, or NLP inventories. The examples provided are generic examples and may not apply to the specific substance you are viewing. IDENTIFICATION Fumaric Acid is a colorless to white, odorless, crystalline powder. For a detailed overview on identified uses and environmental releases, please consult the registered substance factsheet. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. Other Classifications: WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC). Pennsylvania RTK: Fumaric acid Massachusetts RTK: Fumaric acid TSCA 8(b) inventory: Fumaric acid CERCLA: Hazardous substances. 2(b)(i) - Hazardous Agents, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, Workplace Signs - minimum requirements & signs on containers and pipes, Substances of very high concern identification, Recommendation for the Authorisation List, Getting started with EU chemicals legislation, Classification of substances and mixtures, Harmonised classification and labelling (CLH). Substances may have impurities and additives that lead to different classifications. 2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. Philip Lutze, in Distillation, 2014. Fumaric acid … Skin: Causes mild skin irritation. It has a fruit-like taste and has been used as a food additive. The salts and esters are known as fumarates.Fumarate can also refer to the C 4 H 2 O 2− 4 ion (in solution). 0000000913 00000 n Fumarsäure . It is recommended that all dust RTECS # LS9625000 ... Synonyms. Fumaric acid is an organic compound with the formula HO 2 CCH=CHCO 2 H. A white solid, fumaric acid occurs widely in nature. 110-16-7 Revision Date 2007-03-01 New Jersey Right To Know Components Maleic acid CAS-No. This site is not fully supported in Internet Explorer 7 (and earlier versions). In addition, adverse effects on the eye were reported in an in vivo eye irritation study. In such a case, the victim should be allowed to stand in a well-ventilated area. This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. HAZARDS IDENTIFICATION Hazards Not Otherwise Classified: No information available Signal Word: WARNING OSHA Classification: Hazard Category: Hazard Statement: Eye Damage/Irritation 2A Causes serious eye irritation. Here you can find all of the regulations and regulatory lists in which this substance appears, according to the data available to ECHA. Msds Fumaric Acid - Free download as PDF File (.pdf), Text File (.txt) or read online for free. 215–540–4, is covered by three harmonisations: 005–011–00–4; 005–011–01–1 and 005–011–02–9), CLH information cannot be displayed in the InfoCard as the difference between the CLH classifications requires manual interpretation or verification. Possibility of dust explosion. This section is based on three sources for information (harmonised classification and labelling (CLH), REACH registrations and CLP notifications). P264 Wash hands thoroughly after handling. However, substance notifications in the InfoCard are aggregated independently of the impurities and additives. Fumaric acid | C4H4O4 | CID 444972 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. 2. SECTION 6 : Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. This substance is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014, Registration, Evaluation, Authorisation and Restriction of Chemicals, Chemical Agents Directive and Carcinogens or Mutagens Directive, Plastic Materials and Articles Regulation, Safety and/or Health Signs at Work Directive, EC Inventory, Pre-Registration process, CAD - Chemical Agents Directive, Art. This section provides an overview of the calculated volume at which the substance is manufactured or imported to the European Economic Area (EU28 + Iceland, Liechtenstein and Norway). fumaric acid 110-17-8 > 99 Section 4 - FIRST AID MEASURES SWALLOWED If swallowed do NOT induce vomiting. SLIGHTDust explosion possible if in powder or granular form, mixed with air.FUMARIC ACID is a carboxylic acid. Tool showing an overview of substances in various key regulatory processes that authorities are working on. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. This substance is used for the manufacture of: machinery and vehicles, furniture and electrical, electronic and optical equipment. Fumaric acid: Catalog No. Hazardous Substances - Art. trailer 0000004103 00000 n Potential Health Effects Eye: Causes moderate eye irritation. Furthermore, some substances can be found in an article, but with unlikely exposure (e.g. 2; H319 <= 100 % EC-No. Hazards Identification. SARA 311/312 Hazards Acute Health Hazard Massachusetts Right To Know Components Maleic acid CAS-No. 10.3 Possibility of hazardous reactions. If at least one company has indicated that the substance classification is affected by impurities or additives, this will be indicated by an informative sentence. This substance is used in the following products: polymers, adhesives and sealants, coating products, inks and toners and pharmaceuticals. 110-16-7 Revision Date 2007-03-01 Pennsylvania Right To Know Components Maleic acid CAS-No. Exposure to moist air or water. Statements 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and Use descriptors are adapted from ECHA guidance to improve readability and may not correspond textually to descriptor codes described in Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment. The POPs Regulation bans or severely restricts the production and use of persistent organic pollutants in the European Union. Additionally, if available, information on the use of the substance and how consumers and workers are likely to be exposed to it can also be displayed here. The EC or list number is the primary substance identifier used by ECHA. There is no data available. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use. The EC Number is the numerical identifier for substances in the EC Inventory. Use of water jet may cause explosive dust conditions. 0000004719 00000 n The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). Welcome to PubChem! Gives off irritating or toxic fumes (or gases) in a fire. If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. Welcome to the ECHA website. As a food additive, it is used as an acidity regulator and can be denoted by the E number E297. 2(b)(i) - Hazardous Agents, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, Workplace Signs - minimum requirements & signs on containers and pipes, C&L Inventory, Pre-Registration process, CAD - Chemical Agents Directive, Art. Chronic: Not expected to be a chronic hazard. Union List of Authorized Substances: Annex I, Plastics Food Contact Regulation 10/2011/EU, as amended by Regulation 2020/1245/EU, 3 September 2020, EU. Information on applicable regulatory frameworks is also automatically generated and may not be complete or up to date. * Contact can irritate and burn the skin and eyes. It is generally used in beverages and baking powders for which requirements are placed on purity. Fumaric acid is sometimes found in processed foods such as smoked meats. * Breathing Fumaric Acid can irritate the nose and throat causing coughing and wheezing. 7.1. This directive requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. Fumaric Acid Flinn Scientific, Inc. P.O. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). Commission Regulation (EU) No 2015/830 of 28 May 2015. What is the Classification and Labelling Inventory? Other Classifications: WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC). BPR regulation aims to improve the functioning of the biocidal products market in the EU, while ensuring a high level of protection for humans and the environment. Fumaric Acid | Structure, Uses, Hazards, & Properties | - Genuine chemistry - The ultimate resource for Chemistry. Fumaric acid is stable although it is subject to degradation by both aerobic and anaerobic microorganisms. Fumaric Acid E297 is often used as an acidulant and acidity regulator in beverages, pudding mixes, etc. This substance is used in the following products: laboratory chemicals, adhesives and sealants, plant protection products, inks and toners and pH regulators and water treatment products. Fumaric acid Revision Date 26-Jan-2018 Sensitivity to Mechanical ImpactNo information available Sensitivity to Static DischargeNo information available Specific Hazards Arising from the Chemical Fine dust dispersed in air may ignite. S 28A After contact with skin, wash immediately with plenty of water 607-146-00-X For the full text of the H-Statements mentioned in this Section, see Section 16. FUMARIC ACID: ICSC: 1173 (E)-2-Butenedioic acid trans-1,2-Ethylenedicarboxylic acid Allomaleic acid Boletic acid: June 2011: CAS #: 110-17-8 EC Number: 203-743-0 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Combustible. Occupational exposure limit (OEL) values are derived within two legal frameworks that form an integral part of the EU’s mechanism for protecting the health of workers. Fumaric acid 110-17-8 100 Toxicological Data on Ingredients: Fumaric acid: ORAL (LD50): Acute: 10700 mg/kg [Rat]. More information about Classification and Labelling is available in the Regulations section of ECHA website. 0000046174 00000 n Product Identification. 2(b)(i) - Hazardous Agents, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, Workplace Signs - minimum requirements & signs on containers and pipes, kwas trans-etyleno-1,2-dikarboksylowy (pl), C&L Inventory, Registration dossier, Other, fumaric acid ,Butenedioic acid , Allomaleic acid , Boletic acid , Donitic acid , Lichenic acid, EC Inventory, C&L Inventory, Registration dossier, Pre-Registration process, Other, CAD - Chemical Agents Directive, Art. This information is only displayed if the substance is well-defined, its identity is not claimed confidential and there is sufficient information available in ECHA’s databases for ECHA’s algorithms to generate a molecular structure. Information on precautionary measures and the safe use is submitted by the registrant of a substance and the registrant is solely responsible for its accuracy and completeness. +49 34291 3372-36 Fax. * Fumaric Acid may damage the kidneys. At sufficiently high doses the material may be nephrotoxic(i. e. ... fumaric acid ,Butenedioic acid , Allomaleic acid , Boletic acid , Donitic acid , Lichenic acid . Release to the environment of this substance can occur from industrial use: manufacturing of the substance, in the production of articles, as an intermediate step in further manufacturing of another substance (use of intermediates), for thermoplastic manufacture and of substances in closed systems with minimal release. It is approved for use as a food additive in the EU, USA and Australia and New Zealand. Hazard classification & labelling Hazard classification and labelling. : 110-17-8 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, manufacture of substances. in case of consumer and professional uses). +49 34291 3372-36 Fax. Safety Data Sheet (Fumaric Acid) DATE PREPARED: 12/10/2015 Page 2 of 7 Section 3. They react in this way with all bases, both organic (for example, the amines) and inorganic. While fumaric acid itself may be safe, remember that there's risk associated with eating some of the foods in which it appears. The CAS number is the substance numerical identifier assigned by the Chemical Abstracts Service, a division of the American Chemical Society, to substances registered in the CAS registry database. DERMAL (LD50): Acute: 20000 mg/kg [Rabbit]. Fumaric acid or trans-butenedioic acid has the formula HOOC-CH=CH-COOH (C 4 H 4 O 4). If the substance was not covered by the EC Inventory, ECHA attributes a list number in the same format, starting with the numbers 6, 7, 8 or 9. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. Eliminate Any Ignition Until The Area Is Determinded To Be Free From Explosion Or Fire Hazards. Y]����Uǃ[�nШ뾛%4Ne���]ֵ���?5��!��! Public (risk management) activities co-ordination table. Such notifications are required for hazardous substances, mixtures, or articles, manufactured or imported at over 1 kg per annum. Pennsylvania RTK: Fumaric acid Massachusetts RTK: Fumaric acid TSCA 8(b) inventory: Fumaric acid CERCLA: Hazardous substances. P264 Wash hands thoroughly after handling. 0000007878 00000 n Articles of fumaric acid are included as well. Ingestion: No hazard expected in normal industrial use. Registration dossier . 0000000016 00000 n Hazardous overview: Fumaric Acid is Slightly hazardous in case of inhalation, skin contact, ingestion or eye contact. : 682001: Relevant identified uses of the substance or mixture: Identified: Laboratory chemical uses: R&D: Uses advised against: HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. 1.3 Details of the supplier of the safety data sheet Company: MedChemExpress USA Tel: 609-228-6898 Fax: 609-228-5909 This information has not been reviewed or verified by ECHA, and may change without prior notice. 0000001405 00000 n FUMARIC ACID CRS(110-17-8) LC50 fishes 1 245 mg/l LC50-96 Hour - fish (48h) EC50 Daphnia 1 204 - 220 mg/l EC50 - 48 Hour - Daphnia magna 12.2. Fumaric acid and its sodium salts damage the kidney, digestivesystem and liver, and cause flushing. Fumaric acid According to Regulation (EC) No 1907/2006, Annex II, as amended. If the substance is covered by more than one CLH entry (e.g. GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910 0000005379 00000 n Harmonisation is based on the substance’s physical, toxicological and eco-toxicological hazard assessment. Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. Product name : Fumaric acid Catalog No. Fumaric acid has been used as a food acidulant since 1946. 0000002258 00000 n National regulations Germany Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. Containers of Fumaric Acid may be hazardous when empty since they retain product residues (dust, solids); observe all … Fumaric acid-1,4-13 C 2,2,3-d 2 2 Product Results | Match Criteria: Product Name : 203-743-0 Molecular Weight: 116.07 Chemical Formula: HOOCCH=CHCOOH . Note that this list is not exhaustive. The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. CAS 110-17-8, EC Number 203-743-0, chemical formula HOOCCHCHCOOH. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. Carboxylic acids donate hydrogen ions if a base is present to accept them. 5.2 SPECIFIC HAZARDS FIRE AND EXPLOSION HAZARD: Possibility of dust explosion. Product Name: FUMARIC ACID Revision Date: 03.06.2019 Page 3 of 6 5. This information is only displayed if the substance is well–defined, its identity is not claimed confidential and there is sufficient information available in ECHA’s databases for ECHA’s algorithms to generate a molecular structure. This acid is an irritant and skin sensitizer. Substances for which classification and labelling data have been notified to ECHA by manufacturers or importers. Fumaric acid-2,3-d2 | C4H4O4 | CID 12201062 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. %PDF-1.5 %���� MALEIC ACID is a colorless to white crystalline solid. The Support section provides tools and practical guidance to companies which have responsibilities under the EU chemicals legislation. 0000003285 00000 n More information about the EC Inventory can be found here. SAFETY DATA SHEET Fumaric Acid Issued: 01/06/2015 Page 2 Signal Word: Warning Hazard Statements: H319 Causes serious eye irritation. The source of the information is mentioned in the introductory sentence of the hazard statements. Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. 66/2010/EC, L 27/1, 30 Jan 2010 (T. 3 of Anx VI to CLP; Candidate List of SVHCs), EU. GHS product identifier Other means of identification Product type Section 1. Maleic acid Revision Date 25-May-2018 Conditions to Avoid Incompatible products. Registration dossier . Release to the environment of this substance can occur from industrial use: formulation of mixtures, in processing aids at industrial sites and in the production of articles. Isolate from incompatible substances. If no EU harmonised classification and labelling exists and the substance was not registered under REACH, information derived from classification and labelling (C&L) notifications to ECHA under CLP Regulation is displayed under this section. Fumaric Acid Trans-butenedioic Acid, trans-1,2-Ethylenedicarboxylic acid 2-Butenedioic acid Allomaleic acid Boletic acid Donitic acid Lichenic acid Solid, White Crystalline. 7. FUMARIC ACID is a carboxylic acid. This substance is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, for intermediate use only. 0000009127 00000 n 0000004027 00000 n Fumaric Acid GHS SDS, MSDS Sheet, Material Safety Data Sheet. Please note: Precautionary measures and guidance on safe use concern the use and handling of the specific substance as such, not of the presence of the substance in other articles or mixtures. For which requirements are placed on the REACH Annex XIV list 15.1.2 potentially dangerous health effects New.. Available, additional information on classification and labelling ( C & L Inventory, but unlikely! Data of a substance, agreed at EU level by Member States dossier... 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May have its use restricted to certain articles or products and therefore not all the may! Of inhalation, skin contact, ingestion or eye contact in the following areas: formulation mixtures! And additives that lead to different Classifications H-Statements mentioned in the EU legislation. When breathed in structure is based on the data available to ECHA by registrants under the Ecolabel... Furniture and electrical, electronic equipment ) to Know Components maleic acid they are cis boiling maleic or...